Simultaneous electrochemical detection of dopamine, catechol and ascorbic acid at a poly(acriflavine) modified electrode

M. Rashid; V. Auger; Zulfiqur Ali

doi:10.1007/978-3-319-00846-2_221

Simultaneous electrochemical detection of dopamine, catechol and ascorbic acid at a poly(acriflavine) modified electrode

M. Rashid
, V. Auger
, Zulfiqur Ali

Senior Leadership Team

Teesside University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Electro polymerized poly(acriflavine) modified gold (Au) electrode has been prepared and used for the electrochemical detection of dopamine (DA) and catechol (CA) without the interference of ascorbic acid (AA). The experimental results demonstrates that, PAF/Au electrode exhibited favorable electron transfer kinetics and electro catalytic activity towards the oxidation of Dopamine and Ascorbic acid in neutral (pH 7.0) and acidic (pH 5.0) conditions. PAF/Au was found be a good mediator for electrochemical oxidation of Ascorbic Acid, Dopamine and Catechol in pH 7.0 and pH 5.0 PBS buffer solutions. In the Differential Pulse Voltammetry study, PAF/Au electrode offers large peak separation, 120mV between AA and DA at pH 7.0 owing to the introduction of positively charged electrostatic barrier generated by PAF film. Similarly, a large peak separation, 380mV between AA and CA was recorded in this experimental study with a RSD of 6.5%.

Original language	English
Title of host publication	XIII Mediterranean Conference on Medical and Biological Engineering and Computing 2013
Editors	Laura Maria Roa Romero
Place of Publication	Cham, Switzerland
Publisher	Springer
Pages	892-895
Volume	41
ISBN (Electronic)	9783319008462
ISBN (Print)	9783319008455
DOIs	https://doi.org/10.1007/978-3-319-00846-2_221
Publication status	Published - 2014
Event	Mediterranean Conference on Medical and Biological Engineering and Computing : Research and Development of Technology for Sustainable Healthcare - Seville, Spain Duration: 25 Sept 2013 → 28 Sept 2013 Conference number: XIII http://www.medicon2013.com/

Publication series

Name	IFMBE Proceedings
Publisher	Springer
Volume	41
ISSN (Print)	1680-0737
ISSN (Electronic)	1433-9277

Conference

Conference	Mediterranean Conference on Medical and Biological Engineering and Computing
Abbreviated title	MEDICON 2013
Country/Territory	Spain
City	Seville
Period	25/09/13 → 28/09/13
Internet address	http://www.medicon2013.com/

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10.1007/978-3-319-00846-2_221

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Rashid, M., Auger, V., & Ali, Z. (2014). Simultaneous electrochemical detection of dopamine, catechol and ascorbic acid at a poly(acriflavine) modified electrode. In L. M. Roa Romero (Ed.), XIII Mediterranean Conference on Medical and Biological Engineering and Computing 2013 (Vol. 41, pp. 892-895). (IFMBE Proceedings; Vol. 41). Springer. https://doi.org/10.1007/978-3-319-00846-2_221

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title = "Simultaneous electrochemical detection of dopamine, catechol and ascorbic acid at a poly(acriflavine) modified electrode",

abstract = "Electro polymerized poly(acriflavine) modified gold (Au) electrode has been prepared and used for the electrochemical detection of dopamine (DA) and catechol (CA) without the interference of ascorbic acid (AA). The experimental results demonstrates that, PAF/Au electrode exhibited favorable electron transfer kinetics and electro catalytic activity towards the oxidation of Dopamine and Ascorbic acid in neutral (pH 7.0) and acidic (pH 5.0) conditions. PAF/Au was found be a good mediator for electrochemical oxidation of Ascorbic Acid, Dopamine and Catechol in pH 7.0 and pH 5.0 PBS buffer solutions. In the Differential Pulse Voltammetry study, PAF/Au electrode offers large peak separation, 120mV between AA and DA at pH 7.0 owing to the introduction of positively charged electrostatic barrier generated by PAF film. Similarly, a large peak separation, 380mV between AA and CA was recorded in this experimental study with a RSD of 6.5\%.",

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booktitle = "XIII Mediterranean Conference on Medical and Biological Engineering and Computing 2013",

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Rashid, M, Auger, V & Ali, Z 2014, Simultaneous electrochemical detection of dopamine, catechol and ascorbic acid at a poly(acriflavine) modified electrode. in LM Roa Romero (ed.), XIII Mediterranean Conference on Medical and Biological Engineering and Computing 2013. vol. 41, IFMBE Proceedings, vol. 41, Springer, Cham, Switzerland, pp. 892-895, Mediterranean Conference on Medical and Biological Engineering and Computing
, Seville, Spain, 25/09/13. https://doi.org/10.1007/978-3-319-00846-2_221

Simultaneous electrochemical detection of dopamine, catechol and ascorbic acid at a poly(acriflavine) modified electrode. / Rashid, M.; Auger, V.; Ali, Zulfiqur.
XIII Mediterranean Conference on Medical and Biological Engineering and Computing 2013. ed. / Laura Maria Roa Romero. Vol. 41 Cham, Switzerland: Springer, 2014. p. 892-895 (IFMBE Proceedings; Vol. 41).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Simultaneous electrochemical detection of dopamine, catechol and ascorbic acid at a poly(acriflavine) modified electrode

AU - Rashid, M.

AU - Auger, V.

AU - Ali, Zulfiqur

N1 - Conference code: XIII

PY - 2014

Y1 - 2014

N2 - Electro polymerized poly(acriflavine) modified gold (Au) electrode has been prepared and used for the electrochemical detection of dopamine (DA) and catechol (CA) without the interference of ascorbic acid (AA). The experimental results demonstrates that, PAF/Au electrode exhibited favorable electron transfer kinetics and electro catalytic activity towards the oxidation of Dopamine and Ascorbic acid in neutral (pH 7.0) and acidic (pH 5.0) conditions. PAF/Au was found be a good mediator for electrochemical oxidation of Ascorbic Acid, Dopamine and Catechol in pH 7.0 and pH 5.0 PBS buffer solutions. In the Differential Pulse Voltammetry study, PAF/Au electrode offers large peak separation, 120mV between AA and DA at pH 7.0 owing to the introduction of positively charged electrostatic barrier generated by PAF film. Similarly, a large peak separation, 380mV between AA and CA was recorded in this experimental study with a RSD of 6.5%.

AB - Electro polymerized poly(acriflavine) modified gold (Au) electrode has been prepared and used for the electrochemical detection of dopamine (DA) and catechol (CA) without the interference of ascorbic acid (AA). The experimental results demonstrates that, PAF/Au electrode exhibited favorable electron transfer kinetics and electro catalytic activity towards the oxidation of Dopamine and Ascorbic acid in neutral (pH 7.0) and acidic (pH 5.0) conditions. PAF/Au was found be a good mediator for electrochemical oxidation of Ascorbic Acid, Dopamine and Catechol in pH 7.0 and pH 5.0 PBS buffer solutions. In the Differential Pulse Voltammetry study, PAF/Au electrode offers large peak separation, 120mV between AA and DA at pH 7.0 owing to the introduction of positively charged electrostatic barrier generated by PAF film. Similarly, a large peak separation, 380mV between AA and CA was recorded in this experimental study with a RSD of 6.5%.

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DO - 10.1007/978-3-319-00846-2_221

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T3 - IFMBE Proceedings

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BT - XIII Mediterranean Conference on Medical and Biological Engineering and Computing 2013

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Rashid M, Auger V, Ali Z. Simultaneous electrochemical detection of dopamine, catechol and ascorbic acid at a poly(acriflavine) modified electrode. In Roa Romero LM, editor, XIII Mediterranean Conference on Medical and Biological Engineering and Computing 2013. Vol. 41. Cham, Switzerland: Springer. 2014. p. 892-895. (IFMBE Proceedings). doi: 10.1007/978-3-319-00846-2_221

Simultaneous electrochemical detection of dopamine, catechol and ascorbic acid at a poly(acriflavine) modified electrode

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